Autoxidation of Toluic Acids Catalyzed by Cobalt and Bromide Ions in Acetic Acid
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چکیده
منابع مشابه
Kinetics of the autoxidation of sulfur(IV) co-catalyzed by peroxodisulfate and silver(I) ions.
The kinetics and mechanism of the reaction between dissolved oxygen and sulfur(iv) was studied in aqueous acidic medium using co-catalysts peroxodisulfate and silver(i) ions. The presence of both catalysts was required to observe measurable rates in the studied process. The reaction rate was determined through following the UV-absorption of hydrated sulfur dioxide, and the trends were determine...
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A mixture of manganese, cobalt and lead para-amino benzoates supported on silica gel is used to catalyze oxidation of xylenes to toluic acids in presence of oxygen or air. Reactions are clean and catalysts can be recovered easily and reused.
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چکیده هدف از این کار بررسی الکترواکسیداسیون کتکول و مشتقات آن در حضور 4-فنیل سمی کاربامازید بوده است اکسیداسیون کتکولها ترکیبات نا پایدار کینونها را تولید می کنند که این ترکیبات می تواند در واکنش مایکل بعنوان پذیرنده نوکلئوفیل عمل نمایند. در ادامه اکسایش کتکولهای (a-c1) را درحضور 4-فنیل سمی کاربامازید در محلول آب/استونیتریل (90/10)بوسیله ولتامتری چرخه ای و کولن متری در پتانسیل ثابت مورد بررسی ...
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Thermodynamic restrictions and simultaneous effects of operational conditions on the homogeneous rhodium-catalyzed carbonylation of methanol are studied in this line of research. It is shown that the general NRTL-Virial model can be appropriated to study thermodynamics of the carbonylation. It is obtained that the reaction is kinetically and thermodynamically reasonable at temperatures abov...
متن کاملOxidative carbonylation of toluene to p-toluic acid catalyzed by rhodium in the presence of vanadium and oxygen
The mechanism and kinetics of the liquid phase, oxidative carbonylation of toluene to toluic acid were investigated. The catalyst system consisted f Rh(acac)3, NH4VO3, trifluoroacetic acid (TFAH), and trifluoracetic anhydride (TFAA). Liquid toluene together with gaseous CO and O2 was sed as the reactant. The effects of temperature, the partial pressures of O2 and CO, the concentrations of TFAH ...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1975
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.48.1563